Remarkable Influence of Structures around Rhenium (V) Centers Constructed in Polyoxotungstates for Methanol Dehydrogenation under Visible Light Irradiation
Chika Nozaki Kato, Ryuta Nakayama, Shota Hattori, Hidekuni Amano & Yuki Makino · Current Journal of Applied Science and Technology · 2014
The synthesis and characterization of α1-Dawson-type mono-rhenium (V)-substituted polyoxotungstate, [α1-P2W17ReVO62]7- (1), are described. The dimethylammonium salt of 1, [Me2NH2]7[α1-P2W17ReVO62]•9H2O (Me2NH2-1), was obtained as analytically pure homogeneous black-blue crystals...
Open access
Research Article
10.9734/BJAST/2014/9336