The kinetics of the reduction of 3,7-bis(dimethylamino)phenazothionium chloride (MB+) by benzenethiol in aqueous solution has been investigated in the acid range 0.3≤[H+ ≤ 0.9 mole dm-3, ionic strength (µ) of the reaction medium in the range: 0.4 ≤ µ ≤ 1.0 mole dm-3 (NaNO3) and...
Open access
Research Article10.9734/ACSJ/2015/11703
The kinetic investigations of the redox reaction between malachite green, MG+, and hypochlorite ion, ClO–, were carried out in aqueous HClO4 medium at [H+] = 1x10–3 mol dm–3, µ = 0.1 mol dm–3, T = 25±1°C. The reaction showed a stoichiometry of 1:2, which conforms to the equati...
The kinetics of the oxidation of malachite green, MG+, by dithionite ions, S2O42- have been studied spectrophotometrically in an aqueous acid free medium. The investigation was carried out under pseudo- first order conditions of an excess of dithionite concentration. Reaction con...
Open access
Research Article10.9734/IRJPAC/2015/12428
The kinetics of the periodate (IO4–) oxidation of malachite green (MG+) have been studied in aqueous acidic medium. The observed results at [H+] = 1 x 10–4 mol dm–3 (HCl), ionic strength of reaction medium, I = 0.5 mol dm–3 and T = 25.5±0.3°C are consistent with the rate law: −d[...
Open access
Research Article10.9734/JSRR/2015/12423