Nobuaki Tanaka

Matrix Isolation and Theoretical Study on the Photolysis of CH2ClCOCl

Nobuaki Tanaka & Mayuko Nakata · International Research Journal of Pure and Applied Chemistry · 2014

UV light photolysis of chloroacetyl chloride (CH2ClCOCl) has been investigated using infrared spectroscopy in cryogenic Ar, Kr, Xe and O2 matrices. In all matrices, CHCl=C=O, HCl, CH2Cl2 and CO were produced, with the relative yields depending on the used matrix gas. The relative...

Open access Research Article 10.9734/IRJPAC/2014/12002

Matrix Isolation and Computational Studies of Benzoyl Chloride Photolysis

Nobuaki Tanaka · International Research Journal of Pure and Applied Chemistry · 2014

The UV light photolysis (λ >260 nm) of benzoyl chloride was investigated using matrix isolation FT-IR spectroscopy and computational methods (MP2, B3LYP, CCSD, and SAC-CI). The photolysis products were found to bechlorobenzene and CO. An intermediate species was identified wit...

Open access Research Article 10.9734/IRJPAC/2014/11796