Synthesis, Characterization and DNA Binding Studies of (E)-1-((Pyridin-2-yl)methylidene) semicarbazide Mn(II), Co(II), Ni(II) and Cu(II) Complexes
Oinam U-wang, R. K. Bhubon Singh, W. Bembee Devi, U. Ibotomba Singh, R. K. Bindiya Devi, O. Bijeta Devi, Ramina ., Th. Surchandra Singh, Toka Swu
Chemical Science International Journal · pp. 1–19 · Published 27 Mar 2019
10.9734/CSJI/2019/v26i230091Abstract
(E)-1-((pyridin-2-yl)methylidene)semicarbazide (PMSC) complexes of [Mn(PMSC)2 ]Cl2 (1), [Co(PMSC)2]Cl2 (2), [Ni(PMSC)2]Cl2.5H2O (3), and [Cu(PMSC)(H2O)]Cl2 (4) have been synthesized and characterized by different spectroscopic techniques, EPR, magnetic susceptibility and thermal stability measurements. Complex 3 crystallizes as octahedral coordination complex in monoclinic crystal system. Complexes 1 and 2 have been found to have octahedral geometries and 4 to have square planar geometry. The complexes were found to be groove binding to calf-thymus DNA.
Cited by 2
Ramina, Rajkumar Bhubon Singh, Oinam U-wang · Asian Journal of Chemistry · 2020
F. Martínez-Álvarez, G. Asencio-Cortés, J. F. Torres · Big Data · 2020
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