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Synthesis of [Oxa-, Thia-diazoles- and Triazole]-Thiols Derived from Butyric Acid: Conductivity Property, Complex Formation with Fe (II), Hg (II), and Synthesis of Seco-Acyclo-S-Glycosides

Djilali Boulerba, Adil A. Othman, Mohamed B. Taouti

Chemical Science International Journal · pp. 1–9 · Published 14 Apr 2017

10.9734/CSJI/2017/32468

Abstract

Three heterocyclic thiols:  2- propyl-1.3.4 – oxadiazole-5-thione/thiol 4/7,   2- propyl-1.3.4 – thiazole-5-thiole 8, 3- propyl-1.2.4 – triazole-5-thiole 9 have been synthesized from butyric acid. They showed conductivity properties and complex formation with Fe (II) and Hg (II) ions. New S-seco-acyclo-glycosides namely: 2-propyl -1,3,4-oxadiazole-5-thionyl-(1,3-dioxanyl) glycoside 12, 2-propyl -1,3,4-thiadiazole-5-thionyl-(1,3-dioxanyl) glycoside 13 and 3-propyl -1,2,4-triazole-5-thionyl-(1,3-dioxanyl) glycoside14 were synthesized from 7,8,9. Synthesis of nucleobases-complexes with Fe+2 and Hg+2 ions 15-20were achieved. Characterization of synthesized compounds were done by IR and1H-NMR spectroscopy. Potential conductivity of synthesized complexes were determined.

Butyric acid 1,3,4-oxadiazole 1,3,4-thiadiazole 1,2,4-triazole glycosides organometallic complexes conductivity

Cited by 2

Synthesis, characterization and study some of physical properties of novel 1,3,4-oxadiazole derivatives

Nour Abd Alrazzak · IOP Conference Series: Materials Science and Engineering · 2018

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