Spectroscopic Investigation and Magnetic Study of Iron, Manganese, Copper and Cobalt-doped Hydroxyapatite Nanopowders
Physical Science International Journal · pp. 137–151 · Published 15 Jun 2015
10.9734/PSIJ/2015/18676Abstract
Pure, Mn+2, and Fe+3- doped hydroxyapatite (HAp) nanoparticles were synthesized by the wet chemical method. Another two samples were prepared by mixing Mn+2 with Cu+2 into HAp (Mn-Cu HAp) and Fe+3 with Co+2 into HAp (Fe-Co HAp). All samples were prepared without change in the stoichiometric ratio of Ca/P inside the structure of HAp. Samples were characterized by different types of techniques such as XRD, FTIR, ESR, SEM, and EDX. The measurements revealed that a typical HAp powder patterns were obtained. Comparing with pure HAp, Mn+2 substituted HAp (Mn-HAp) and Fe+3 substituted HAp (Fe-HAp) did not demonstrate significant structure deviation. Since the ion exchange mechanism was achieved for the preparation process, the morphology and particle size were not significantly affected but the calculated crystallinity index (CI) values were affected. The absorption spectra of the doped samples are presented as absorption bands a typical Mn+2, and Fe+3 occupying to different crystalline sites. The obtained data agrees well with that obtained from XRD. The crystal field parameters and crystallinity index for sites of these ions in the HAp matrix were calculated. SEM analysis indicated that nanoparticles aggregates were formed. EPR properties make the studied sample to be used in the field of hyperthermia application.
References (23)
- 1 Magnetic Nanoparticles: Synthesis, Protection, Functionalization, and Application [DOI]
- 2 Applications of Magnetic Nanoparticles in Biomedicine [DOI]
- 3 Titanium in Medicine [DOI]
- 4 Structure and properties of nano-hydroxyapatite/polymer composite scaffolds for bone tissue engineering [DOI]
- 5 The role of collagen in bone apatite formation in the presence of hydroxyapatite nucleation inhibitors [DOI]
- 6 Differential Burning, Recrystallization, and Fragmentation of Archaeological Bone [DOI]
- 7 Characterization of hydroxyapatite and carbonated apatite by photo acoustic FTIR spectroscopy [DOI]
- 8 Calcium phosphate coatings on magnesium alloys for biomedical applications: A review [DOI]
- 9 Nanosized hydroxyapatite and other calcium phosphates: Chemistry of formation and application as drug and gene delivery agents [DOI]
- 10 Hydroxyapatite nanorods as novel fillers for improving the properties of dental adhesives: Synthesis and application [DOI]
- 11 In situ synthesis and biocompatibility of nano hydroxyapatite on pristine and chitosan functionalized graphene oxide [DOI]
- 12 THE POTENTIAL OF FERUMOXYTOL NANOPARTICLE MAGNETIC RESONANCE IMAGING, PERFUSION, AND ANGIOGRAPHY IN CENTRAL NERVOUS SYSTEM MALIGNANCY [DOI]
- 13 Osteoinductive hydroxyapatite-coated titanium implants [DOI]
- 14 Effects of hydroxyapatite reinforcement on the architecture and mechanical properties of freeze-dried collagen scaffolds [DOI]
- 15 Fe2+/Fe3+ substitution in hydroxyapatite: Theory and experiment [DOI]
- 16 Electron paramagnetic resonance (EPR) biodosimetry [DOI]
- 17 Synthesis of strontium substituted hydroxyapatite whiskers used as bioactive and mechanical reinforcement material [DOI]
- 18 In Vitro Biocompatibility and Osteoblast Differentiation of an Injectable Chitosan/Nano‐Hydroxyapatite/Collagen Scaffold [DOI]
- 19 In vitro evaluation of amorphous calcium phosphate and poorly crystallized hydroxyapatite coatings on titanium implants [DOI]
- 20 Optical and structural properties of undoped and Mn2+ doped Ca–Li hydroxyapatite nanopowders using mechanochemical synthesis [DOI]
- 21 Mechanochemical Synthesis of Hydroxyapatite and Its Modifications: Composition, Structure, and Properties [DOI]
- 22 Characterization of in situ prepared nano‐hydroxyapatite/polyacrylic acid (HAp/PAAc) biocomposites [DOI]
- 23 Fundamentals of Hydroxyapatite and Related Calcium Phosphates [DOI]
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