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All published articles 998

A Graphene Oxide Nanoprobe for Sensitive Fluorescent Telomerase Activity Analysis

Bin Zhu, Ruiguo Cao, Yuanyuan Jiang, Qi Li, Qiang Zhang, Gu Yuan, Jingjian Li & Dongsheng Xu · International Research Journal of Pure and Applied Chemistry · 2014

A novel fluorescent biosensor with ultra-sensitivity and selectivity for telomerase detection has been designed based on oligonucleotide-adsorption to graphene oxide (GO). This PCR-free method employs fluorescent ssDNA as a probe, which exhibits minimal background fluorescence in...

Open access Research Article 10.9734/IRJPAC/2014/12197

Biosorption of Copper from Aqueous Solutions by Raw and Activated Spines of Bombax buonopozense: Equilibrium, Kinetics and Thermodynamic Studies

S. Mustapha, B. E. N. Dauda, M. M. Ndamitso, T. J. Mathew, U. Bassey & S. S. Muhammed · International Research Journal of Pure and Applied Chemistry · 2014

Biosorption of copper on raw and activated (AC) spines of Bombax buonopozense in a batch system was studied. The percentage removal of copper was found to be a function of pH, contact time, dosage, initial metal concentration and temperature. The experimental results were analyze...

Open access Research Article 10.9734/IRJPAC/2014/12083

Selected Trace Heavy Metals Concentrations in Well and Borehole Water in Aliero Metropolis

I. S. Shabanda, S. A. Kilgori, S. Umar & M. H. Aminu · International Research Journal of Pure and Applied Chemistry · 2014

Human activities had been the major causes of water pollution, and the presence of heavy metals could be an indicator that water bodies are polluted. This research examined the concentration of heavy metals in well and bore hole water from three different areas (Bodiga, Labana fa...

Open access Research Article 10.9734/IRJPAC/2014/11640

Improvement of Paper Properties of Rice Straw Pulps by Microcrystalline Cellulose/Calcium Carbonate

Mona A. Nassar & M. H. El Shakankery · International Research Journal of Pure and Applied Chemistry · 2014

Rice straw is a locally available lignocellulosic material. In this study rice straw was pretreated by soaking it in water for 48 hours at room temperature. The pretreated straw was cooked in 5% NaOH at 100ºC and atmospheric pressure. The structure and mechanical properties of pa...

Open access Research Article 10.9734/IRJPAC/2014/7347

Chemical Analysis of Iron Slags and Metallic Artefacts from Early Iron Age

Almir Olovčić, Mustafa Memić, Sabina Žero, Jasna Huremović & Emira Kahrović · International Research Journal of Pure and Applied Chemistry · 2014

Eight samples of iron slag and two metallic artefacts from two Early Iron Age sites in central Bosnia and Herzegovina, Čolaci and Pod, were analysed using chemical instrumental methods. Atomic absorption spectrometry was applied to determine major (Fe, Al, Ca, Na, Mg, K and Mn) a...

Open access Research Article 10.9734/IRJPAC/2014/12248

Redox Kinetics and Mechanism of the Oxidation of Thiourea by Diaquotetrakis(2,2’- Bipyridine) - µ - Oxodiruthenium (III) Ion, in Aqueous Perchloric Acid

Yahaya Mohammed, Sulaiman O. Idris & Johnson F. Iyun · International Research Journal of Pure and Applied Chemistry · 2014

The kinetics of the oxidation of thiocarbamide (thiourea) by diaquotetrakis(2,2’- bipyridine) - µ - oxodiruthenium (III) ion, [(bpy)2(H2O)RuORu(H2O)(bpy)2]4+, in perchloric acid has been investigated at a temperature, T = 30±1ºC, ionic strength, I = 0.5 mol dm-3 (NaClO4) and hydr...

Open access Research Article 10.9734/IRJPAC/2014/11517

Kinetics of Oxidation of Diazepam by N Bromosuccinimide in Acid Medium: A Mechanistic Study

N. Nanda, S. Malini, Puneeth Kumar & Netkal M. Made Gowda · International Research Journal of Pure and Applied Chemistry · 2014

The oxidation of diazepam (DZ) by N-Bromosuccinimide (NBS) in aqueous acid medium follows a first-order kinetics in [NBS] and a fractional-order each on [HCl] and [DZ].  The reaction stoichiometry involves one mol NBS consumed by one mol DZ.   The rate of the reaction increases w...

Open access Research Article 10.9734/IRJPAC/2014/10534

Electrochemical Studies of Copper Corrosion Inhibition in Aqueous Solution by Basic Red 46 Dye and Evaluation of the Inhibitor Adsorption Behavior

Habib Ashassi-Sorkhabi, Elnaz Asghari & Rana Bakhshi · International Research Journal of Pure and Applied Chemistry · 2014

Aims: The corrosion inhibition performance of an organic dye, Basic Red 46, was studied against the corrosion of copper in 1M HCl. The adsorption isotherm of the used dye was also evaluated. Study Design: Electrochemical methods were used for this study. The corrosion of copper s...

Open access Research Article 10.9734/IRJPAC/2014/12330

Removal of Trace Metals from Aqueous Solution by Fe(OH)3 Coprecipitation and Flotation Using Poly-Glutamic Acid

Le Thi Xuan Thuy, Le Phuoc Cuong & Tomoki Yabutani · International Research Journal of Pure and Applied Chemistry · 2014

Iron hydroxide (Fe(OH)3) coprecipitation and an eco-friendly flotation technique by use of gamma poly-glutamic acid (γ-PGA) was developed for removal of heavy metals from water. Effects of PGA concentration and the flotating time on the flotation of Fe(OH)3 precipitate and remova...

Open access Research Article 10.9734/IRJPAC/2014/10936

Study of Starch Based Biodegradable Polymeric Surfactants for Better Cleansing Activity

Md. Ibrahim H. Mondal, Md. Mohsin Hossain & Md. Raihan Sharif · International Research Journal of Pure and Applied Chemistry · 2014

In the present case, biodegradable starch interactions with various surfactants have been studied for the investigation of ability and cleansing activity of the starch-surfactant-water system. The surfactants investigated were sodium dodecyl sulphate (SDS) sodium octanoate (NaOct...

Open access Research Article 10.9734/IRJPAC/2014/10562

Hysteretic Desorption of Perfluorooctane Sulphonates within Sediment Components under Aerobic and Anoxic Conditions

I. A. Ololade · International Research Journal of Pure and Applied Chemistry · 2014

The fate of organic contaminants in sediment can be better accurately predicted through knowledge of desorption. Complex formation between perflurooctane sulphonates (PFOS) and active sites on sediment components, especially, the level of organic matter plays significant role in...

Open access Research Article 10.9734/IRJPAC/2014/10592

Electronic Transport at Low Temperature in Ni/Al/Ni Films

R. Ramanna, P. J. Sadashivaiah, T. Sankarappa, T. Sujatha, J. S. Ashwajeet, A. W. Manjunath & Santosh Kori · International Research Journal of Pure and Applied Chemistry · 2014

A series of sandwiched films in the configuration, Ni(100nm)/Al(t)/Ni(100nm); t = 10nm, 20nm,……, 100nm (labeled as NAN1, NAN2, ………, NAN10) were deposited by thermal and electron beam gun evaporation techniques. The films were deposited onto the glass substrates held at 473K, unde...

Open access Research Article 10.9734/IRJPAC/2014/11187

Matrix Isolation and Theoretical Study on the Photolysis of CH2ClCOCl

Nobuaki Tanaka & Mayuko Nakata · International Research Journal of Pure and Applied Chemistry · 2014

UV light photolysis of chloroacetyl chloride (CH2ClCOCl) has been investigated using infrared spectroscopy in cryogenic Ar, Kr, Xe and O2 matrices. In all matrices, CHCl=C=O, HCl, CH2Cl2 and CO were produced, with the relative yields depending on the used matrix gas. The relative...

Open access Research Article 10.9734/IRJPAC/2014/12002

Matrix Isolation and Computational Studies of Benzoyl Chloride Photolysis

Nobuaki Tanaka · International Research Journal of Pure and Applied Chemistry · 2014

The UV light photolysis (λ >260 nm) of benzoyl chloride was investigated using matrix isolation FT-IR spectroscopy and computational methods (MP2, B3LYP, CCSD, and SAC-CI). The photolysis products were found to bechlorobenzene and CO. An intermediate species was identified wit...

Open access Research Article 10.9734/IRJPAC/2014/11796

Assessment of Phytoconstituents and Antidiabetic Activity of the Crude Extract and Partitioned Fractions of Maytenus senegalensis (Lam.) Exell (Celastraceae) Root Bark

Abdullahi Mann, Fatimah Opeyemi Roheem, Abubakar N. Saidu, Jonathan Yisa, Labake A. Fadipe & Emmanuel O. Ogbadoyi · International Research Journal of Pure and Applied Chemistry · 2014

Aims: To investigate the antidiabetic activity of the root bark of Maytenus senegalensis ethnomedically used in Nupeland for the management of diabetes and isolate phytoconstiteunts responsible for the pharmacological activities. Study Design: Air-dried root bark Maytenus senegal...

Open access Research Article 10.9734/IRJPAC/2014/8616