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All published articles 998

Application of Newton’s Zero Order Caustic for Analysis and Measurement: Part-I Absorbance

Antonio A. Garcia, Luis Nuñez, Charles John, Habtom Hadish, Victor Orioke & Vladimiro Mujica · International Research Journal of Pure and Applied Chemistry · 2013

When light is incident upon a liquid solution droplet containing a light absorbing solute and it is formed into a spheroid shape, absorbance can be measured and related to concentration of the light absorbing species in a manner analogous to standard spectrophotometry. However, t...

Open access Research Article 10.9734/IRJPAC/2014/5897

Azamacrocycle Complexes: Synthesis and Xanthine Oxidase and Antioxidant Activity

A. Bushra Begum, V. Lakshmi Ranganatha, T. Prashanth, M. S. Asha, Farhan Zameer, Raghavendra Hegdekatte & Shaukath Ara Khanum · International Research Journal of Pure and Applied Chemistry · 2013

Aims: Gout is caused by high uric acid in the blood that leads to excess uric acid crystallizing in the joints causing swelling and pain. Uric acid is produced from the breakdown of the purine which is released when cells die or introduced from the food we eat. The enzyme that he...

Open access Research Article 10.9734/IRJPAC/2014/5355

Kinetics and Mechanism of Oxidation of Gabapentin by N-bromosuccinimide in Aqueous Alkaline Medium. Comparing to the Kinetics of Oxidation by N-bromosuccinimide in Aqueous Acid Medium

Alaa Eldin Mokhtar Abdel-Hady · International Research Journal of Pure and Applied Chemistry · 2013

The kinetics of oxidation of gabapentin (GBP) by N-bromosuccinimide (NBS) in an alkaline medium has been investigated. The oxidation reaction showed unique kinetics that greatly differed on going from acid to base medium.  In an acid medium (pH=2.52), the reaction rate showed fir...

Open access Research Article 10.9734/IRJPAC/2014/6175

QSAR Analysis of Some TIBO Derivatives As HIV-1 Reverse Transcriptase Inhibitors

Lokendra Kumar Ojha, Ajay M. Chaturvedi, Arpan Bhardwaj, Mamta Thakur & Abhilash Thakur · International Research Journal of Pure and Applied Chemistry · 2013

We performed studies to correlate the biological activity of the TIBO (4,5,6,7-tetrahydro-5-methylimidazo[4,5,1-j,k][1,4] benzodiazepin-2(1H)-one)14 sets of compound with the independent variable (descriptor) to know the structural requirement of the drug receptor binding interac...

Open access Research Article 10.9734/IRJPAC/2013/2817

Bimetallic Aluminum Complexes Modified with Chloride Ions of Mn (II), Fe (III), and Ni (II) for Pyrocondensate Oligomerization

H. C. Ibragimov, E. H. Ismailov, K. M. Gasimova, Yu. H. Yusifov, Z. M. Ibragimova & I. V. Kolchikova · International Research Journal of Pure and Applied Chemistry · 2013

The oligomerization process of pyrocondensate fraction was performed in the presence of catalytic systems which were synthesized by the reaction of aluminium metal (Al) and dichloroethane (DCE) as the basic catalyst and after that were modified with metal chloride of Mn (II), Fe...

Open access Research Article 10.9734/IRJPAC/2013/4757

Stability Constant and Thermodynamic Parameters Determination of A Semi-synthetic Penicillin Derivative with Various Bivalent Metal Ions (Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Sn2+, Hg2+ and Pb2+): A Potentiometric Study

Anita Gupta · International Research Journal of Pure and Applied Chemistry · 2013

This present work is a report on the stability constant values of a worthy antibiotic, Ampicillin Trihydrate; D[-]-α-aminobenzyl penicillin; ABP; a semi-synthetic derivative of penicillin with various biologically vital bivalent metal ions (Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Sn2+, Hg2...

Open access Research Article 10.9734/IRJPAC/2014/5077

Explanatory Interaction Profile of Cd, Pb and Zn on the Relative Abundance of Fe as Response Variable in Drinking Water Quality Assessment

Umar Musa, Maimuna Waziri & Stephen S. Hati · International Research Journal of Pure and Applied Chemistry · 2013

Aims: The present study determined the quality status of drinking water in some locations of Northeastern Nigeria and attempted to present an explanatory interaction profile of Cd, Pb and Zn on the bases of the relative abundance of Fe in the drinking water samples. Study Design:...

Open access Research Article 10.9734/IRJPAC/2013/3924

Quality Parameters of Biodiesel Produced from Locally Sourced Moringa oleifera and Citrullus colocynthis L. Seeds Found in Kaduna, Nigeria

A. O. Aliyu, J. M. Nwaedozie & Ahmed Adams · International Research Journal of Pure and Applied Chemistry · 2013

Oils were extracted from Moringa oleifera and Citrullus colocythis L. (melon) seeds, using soxhlet extractor with n-hexane as solvent. The oil yield were; 51.00% and 50.87% for melon and moringa respectively. The oils physicochemical parameters such as moisture content, density a...

Open access Research Article 10.9734/IRJPAC/2013/4425

EDTA effect on Copper Sulphate Penta Hydrate-A NLO Material

R. Manimekalai & C. Ramachandra Raja · International Research Journal of Pure and Applied Chemistry · 2013

Ethylene Diamine Tetra Acetic acid (EDTA) doped copper sulphate penta hydrate were grown for five different parent-dopant combinations using slow solvent evaporation method at 300 K and good optical quality crystals were harvested for minimum dopant ratio. The single crystal X-ra...

Open access Research Article 10.9734/IRJPAC/2013/5299

Determination of Optimum Catalyst Concentration for Biodiesel Yield from Coconut (Cocos nucifera) Oil

A. U. Ofoefule, C. N. Ibeto & I. E. Ugwuamoke · International Research Journal of Pure and Applied Chemistry · 2013

The determination of optimum catalyst concentration for biodiesel yield from Coconut (Cocos nucifera) oil was studied. The oil was transesterified using potassium methoxide as catalyst to obtain the crude biodiesel. The reaction was carried out at different catalyst concentration...

Open access Research Article 10.9734/IRJPAC/2013/3761

FT-IR Spectroscopic Studies on Coastal Sediment Samples from Nagapattinum District, Tamilnadu, India

S. Sivakumar, R. Ravisankar, A. Chandrasekaran & J. Prince Prakash Jebakumar · International Research Journal of Pure and Applied Chemistry · 2013

The mineralogical characterization was carried out to determine the major and minor constituents minerals present in the coastal sediment collected in and around Nagapattinum district Tamilnadu, India by FT-IR spectroscopy. The minerals were identified with the help of available...

Open access Research Article 10.9734/IRJPAC/2013/4265

Uncatalysed Oxidation of D-(+) Galactose by Cerium (IV) in Aqueous Acidic Medium-A Kinetic and Mechanistic Approach

Manoj Kumar Ghosh & S. K. Rajput · International Research Journal of Pure and Applied Chemistry · 2013

The Kinetics investigation of uncatalysed oxidation of D-(+) galactose by cerium (IV) have been studied in an acidic medium in the temperature range 308-328K. The reaction has been found to be first order with respect to D-(+) galactose in an uncatalysed reaction. The effect of [...

Open access Research Article 10.9734/IRJPAC/2013/3877

Thermodynamics of the Solvation of CaSO4 in Mixed DMF-H2O at 301.15 K

Esam A. Gomaa, Elsayed M. Abou Elleef & M. G. Abdel-Razek · International Research Journal of Pure and Applied Chemistry · 2013

Aims: The aim of this study was to determine the thermodynamics of the solvation of CaSO4 in mixed DMF-H2O at 301.15 K. The Gibbs free energies as very important thermodynamic property were evaluated for CaSO4 in mixed dimethylformamide (DMF)-H2O solvents at 301.15 K from the exp...

Open access Research Article 10.9734/IRJPAC/2013/4344

Adsorption and Thermodynamic Characteristics of Plumeria rubra Plant Extracts on Mild Steel Corrosion in Industrial Water Medium

C. B. Pradeep Kumar & K. N. Mohana · International Research Journal of Pure and Applied Chemistry · 2013

The inhibition effect of Plumeria rubra (PR) extracts on the corrosion of mild steel in industrial water medium was studied by mass loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The results show that the protection efficiency increas...

Open access Research Article 10.9734/IRJPAC/2013/5397

Solid-State Metathetic Synthesis of Phase Pure BaSnO3 and BaZrO3

U. Sujana Kumari, P. Suresh & A. A. V. Prasada Rao · International Research Journal of Pure and Applied Chemistry · 2013

A simple solid state metathetic  synthesis has been developed for the preparation of BaSnO3 and BaZrO3 making use of BaCl2 along with Na2SnO3 and K2[ZrO(C2O4)2].3H2O as precursors. Phase pure compounds in each case were obtained at lower temperatures than those reported in litera...

Open access Research Article 10.9734/IRJPAC/2013/4147