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Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Some Thermodynamic Functions of Saturated Alkanes

Vitaly Ovchinnikov · Chemical Science International Journal · 2013

The correlation equation Dc,f,vapΨo = i + f *N have been used for the description of thermodynamic functions DΨo of free energy, heat, entropy and heat capacity of the combustion, formation and vaporization processes for alkanes of the different space structure. The i and f are s...

Open access Research Article 10.9734/ACSJ/2014/4844

Prediction of Retention in Gradient Reversed-Phase Liquid Chromatography for Phenyl Isothiocyanate-Derivatives of Amino Acids

Jelena Golushko, Svetlana Vorslova, Sergey Galushko, Arturs Viksna & Kristine Edolfa · Chemical Science International Journal · 2013

Aim: To study the applicability of the solvatic retention model for the prediction of retention times in gradient elution of phenylisothiocyanate derivatives of natural amino acids. Methodology: The solvatic retention model of reversed-phase liquid chromatography has been used to...

Open access Research Article 10.9734/ACSJ/2014/6299

FT-Raman Spectroscopy and PLS Regression for Quantitative Determination of Captopril in Tablet Powder; Effect of Different Preprocessing Methods

Ahmed Shawky, Ahmed Ibrahim, Maissa Y. Salem & Ahmed E. El Gindy · Chemical Science International Journal · 2013

Aims: This study was performed to develop a fast and simple method for the quantitative analysis of Captopril in tablet powder by FT-Raman Spectroscopy and PLS regression. The effect of different preprocessing methods on multivariate calibration was studied. Methodology: Four dif...

Open access Research Article 10.9734/ACSJ/2014/6087

Kinetics of the Adsorption of Anionic and Cationic Dyes in Aqueous Solution by Low-Cost Activated Carbons Prepared from Sea Cake and Cotton Cake

Tchakala Ibrahim, Bawa L. Moctar, Kodom Tomkouani, Djaneye- Boundjou Gbandi, Doni K. Victor & Nambo Phinthè · Chemical Science International Journal · 2013

Activated carbons prepared from shea cake (CA-K) and cotton cake (CA-C) were investigated for removal of four dyes in aqueous solutions (0 – 200 mg/L): Reactive Black 5 (RB5), Methylene blue (BM), Reactive Orange 16 (RO16) and Methyl Orange (MO) from water by adsorption. The acti...

Open access Research Article 10.9734/ACSJ/2014/5403

6,11-Bisthia Steroidal Analogues: Synthesis, Characterization, and Evaluation of Antimicrobial-, Antituberculosis-, and Antitumor Activity

Sudalaiandi Kumaresan · Chemical Science International Journal · 2013

Aims: Synthesis, characterization, antimicrobial-, antituberculosis-, and antitumor activity of a few 6,11-bisthiasteroidal analogues have been carried out. Methodology: Subsequent reaction of the mixture 3 with phenylhydrazine hydrochloride/hydrazine hydrochloride under reflux i...

Open access Research Article 10.9734/ACSJ/2014/6269

Studies on Quinolin-2(1H)-One Derivatives: Synthetic Access to Pyrano[3,2-c] Quinoline and 3-Substituted Quinoline Derivatives

Fathy M. A.El-Taweel, Abdel- Ghani A. Elagamey & Muhammad H. M. Khalil · Chemical Science International Journal · 2013

4H-pyrano[3,2-c]quinoline derivatives 6a-f were prepared via reacting arylmethylenemalononitriles 2-c,g with 4-hydroxyquinolines 1a-c or 1e,f. Refluxing  6d  with formic acid or acetic anhydride gave 7-(2-chlorophenyl)-5-methyl-5H-pyrimido [5'4':5,6]pyrano[3,2-c]quinoloine-6,8-(7...

Open access Research Article 10.9734/ACSJ/2013/3318

Mechanical Properties of Wood Waste Reinforced Polymer Matrix Composites

R. O. Medupin, O. K. Abubakre, K. O. Ukoba & P. E. Imoisili · Chemical Science International Journal · 2013

This research work set is an investigation into the mechanical properties of polymer matrix composites (PMC) produced by the use of wood waste. Low density polyethylene was reinforced with sawdust from African teak as a filler, and Sodium hydroxide as the binder. The composite we...

Open access Research Article 10.9734/ACSJ/2013/5637

Spectrophotometric Method for the Determination of Cefotaxime Sodiumand Cefoperazone Sodium in Pure and Pharmaceutical Dosage Forms

Rania Adel Sayed, Wafaa Sayed Hassan, Magda Yossif El- Mammli & Abdalla Shalaby · Chemical Science International Journal · 2013

Accuratespectrophotometric method was developed for the estimation of cefotaxime sodium (I) andcefoperazone sodium (II) in both pure and pharmaceutical dosage forms. The method is based on the reaction of the amino groups of the cited drugs with ninhydrin reagent producing a colo...

Open access Research Article 10.9734/ACSJ/2013/5572

Mechanical Properties of Cocoa-Pod/Epoxy Composite; Effect of Filler Fraction

P. E. Imoisili, T. C. Ezenwafor, B. E. AttahDaniel & S. O. O. Olusunle · Chemical Science International Journal · 2013

In this study the mechanical properties of an agricultural waste (cocoa pod) in a polymer matrix (Epoxy resin) was investigated, and the effect of volume fraction of cocoa pod/epoxy resin composite was also investigated, different filler volume fraction (viz. 5 to 30 weight %) we...

Open access Research Article 10.9734/ACSJ/2013/5526

Thermodynamics of the Solvation of Lead Nitrate in Mixed DMF-H2O Solvents at 301.15 K

Esam A. Gomaa & Elsayed M. Abou Elleef · Chemical Science International Journal · 2013

Aims: The aim of this study is to determine thermodynamic energies of the solvation of lead nitrate in mixed DMF-H2O solvents at 301.15 K. The Gibbs free energies as a very important thermodynamic property were evaluated for Pb(NO3)2 in mixed dimethylformamide DMF-H2O solvents at...

Open access Research Article 10.9734/ACSJ/2013/4343

Solvent Extraction Studies of Uranium (VI) from Aqueous Media into Chloroform Solution of N,N´-ethylenebis(4-propionyl-2,4-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-oneimine)

U. J. Chukwu & J. Godwin · Chemical Science International Journal · 2013

The extraction of Uranium (VI) from aqueous media of varying pH values (0.3 – 9.0) was studied using chloroform solution of 0.05M N,N`-ethylenebis(4-propionyl-2,4-dihydro-5-methyl-2-phenyl-3H- pyrazol-3-oneimine) (H2PrEtP) Schiff base. The effect of 4-propionyl-2,4-dihydro-5-meth...

Open access Research Article 10.9734/ACSJ/2013/4155

Densities, Viscosities and Ultrasonic Studies of Binary Liquid Mixture of Ethylamine and Benzyl Alcohol at Different Temperatures

Chandra Mohan Saxena, Archna Saxena, Ashok Kumar Srivastava & Naveen Kumar Shukla · Chemical Science International Journal · 2013

Ultrasonic studies, densities and viscosities of binary liquid mixture of ethylamine and benzyl alcohol have been measured at different temperatures at 30ºC, 35ºC and 40ºC. The experimental value of speed of sound (u), isentropic compressibility (βs), intermolecular free length (...

Open access Research Article 10.9734/ACSJ/2013/5229

Level of Selected Metals in Water, Sediment and Fish Samples from Itapaji Dam, South-Western, Nigeria

Adefemi Oluyemi Samuel · Chemical Science International Journal · 2013

The level of metals (Zn, Fe, Pb, Cu, Mn, Cr, Na, Mg, Ca and K) in water, sediment and fish samples from Itapaji dam for both dry and wet seasons in two years were determined using standard analytical methods. The concentrations of metals were higher in dry season than those of we...

Open access Research Article 10.9734/ACSJ/2013/4988

Persistent Organochlorine Compounds in the Water and Sediment Samples from the Lake Bosomtwe in Ghana

Samuel Afful, Johannes A.M. Awudza, Shiloh Osae & Stevester K. Twumasi · Chemical Science International Journal · 2013

Aims: To investigate the burden of organochlorine pesticides (OCPs) and its degradation products as well as indicator polychlorinated biphenyl (PCBs) in the water and sediments. Study Design: This investigation involved one year monitoring of the Lake. Place and Duration of Study...

Open access Research Article 10.9734/ACSJ/2013/3913