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Research Article Open access CC BY 3.0

Zinc(II) Complexes Based on ortho-Phthalic Acid and Ancillary N-Donor Ligands

Svetlana G. Baca

International Research Journal of Pure and Applied Chemistry · pp. 1–24 · Published 10 Dec 2011

10.9734/IRJPAC/2012/717

Abstract

The versatile coordination abilities of o-phthalic acid, containing two carboxylic groups in ortho-position, allow for a variety of structures ranging from discrete complexes to 1D, 2D and 3D architectures. This review focuses on the synthesis and structural particularities of zinc(II) phthalates with ancillary N-containing ligands such as pyridine, imidazole and their derivatives [3-, 4-methylpyridine, and 1-, 2-methylimidazole], and 2,2′-, 4,4′-bipyridine. The coordination features manifested by this ligand are analyzed and discussed.  

o-Phthalic acid zinc(II) complexes carboxylates coordination polymers N-donor ligands

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