Kinetics of the Adsorption of Anionic and Cationic Dyes in Aqueous Solution by Low-Cost Activated Carbons Prepared from Sea Cake and Cotton Cake
Tchakala Ibrahim, Bawa L. Moctar, Kodom Tomkouani, Djaneye- Boundjou Gbandi, Doni K. Victor, Nambo Phinthè
Chemical Science International Journal · pp. 38–57 · Published 4 Oct 2013
10.9734/ACSJ/2014/5403Abstract
Activated carbons prepared from shea cake (CA-K) and cotton cake (CA-C) were investigated for removal of four dyes in aqueous solutions (0 – 200 mg/L): Reactive Black 5 (RB5), Methylene blue (BM), Reactive Orange 16 (RO16) and Methyl Orange (MO) from water by adsorption. The activated carbons were prepared by chemical activation using phosphoric acid as activation agent. Chemical characteristics of these activated carbons was monitored by Bohem titration and the method of Lopez-Ramon et al. while surface areas of the samples were determined by nitrogen adsorption/desorption isotherm measurement. Activated carbons CA-K and CA-C have the following characteristics: BET surface and the pore volumes are respectively 1148 m2/g and 0.607 cm3/g for CA-K, 584 m2/g and 0.298 cm3/g for CA-C. The two activated carbons synthesized are microporous activated carbon with micropores volume representing more than 70% of the total pore volume. The removal of dyes was studied using batch reactor. The nature of the activated carbon and the dyes are the key factors influencing the contact time. At the equilibrium times (35 to 270 min for CA-K and 60 to 300 min for CA-C), the removal of BM, MO and RO16 was quasi-total while for RB5 the amount adsorbed was about 83%. Based on the adsorption capacity, it was shown that CA-K was more effective than CA-C. Various kinetic models such as pseudo first-order, pseudo second-order and intraparticle diffusion were used to evaluate the mechanism of dyes adsorption on activated carbons. BM, RO16, and MO removal process was found to be governed by second-order kinetic while pseudo-first order kinetic is suitable for RB5 adsorption study. The pHs of the solutions and the amount of activated carbon have strong effect on the adsorption capacity of these dyes. An acid pH (for anionic dyes) and basic pH (for cationic dyes) were favorable for the maximum adsorption of dyes. The isotherm data could be well described by the Freundlich and Langmuir equations in the concentration range of 0–80 mg/L. For the present adsorption process intraparticle diffusion of dyes within the particle was identified to be rate limiting. Both activated carbons were shown to be promising materials for adsorption removal of dyes from aqueous solutions.
References (41)
- 1 Pseudo-second order model for sorption processes [DOI]
- 2 Zur Theorie der sogenannten Adsorption gelöster Stoffe [DOI]
- 3 Modification of the surface chemistry of activated carbons [DOI]
- 4 Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste [DOI]
- 5 Chemical Identification of Surface Groups [DOI]
- 6 Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon [DOI]
- 7 On the characterization of acidic and basic surface sites on carbons by various techniques [DOI]
- 8 Adsorption behavior of reactive dye in aqueous solution on chemical cross-linked chitosan beads [DOI]
- 9 Adsorption of basic dye (methylene blue) onto activated carbon prepared from rattan sawdust [DOI]
- 10 High surface area activated carbon prepared from cassava peel by chemical activation [DOI]
- 11 Liquid-phase adsorption of dyes and phenols using pinewood-based activated carbons [DOI]
- 12 A novel method for production of activated carbon from waste tea by chemical activation with microwave energy [DOI]
- 13 Adsorption studies of basic dye on activated carbon derived from agricultural waste: Hevea brasiliensis seed coat [DOI]
- 14 Adsorption of dissolved Reactive red dye from aqueous phase onto activated carbon prepared from agricultural waste [DOI]
- 15 2-Steps KOH activation of rice straw: An efficient method for preparing high-performance activated carbons [DOI]
- 16 Equilibrium, kinetics and thermodynamic of Remazol Brilliant Orange 3R dye adsorption on coffee husk-based activated carbon [DOI]
- 17 Effects of acidic treatment of activated carbons on dye adsorption [DOI]
- 18 Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud [DOI]
- 19 Wastewater treatment using low cost activated carbons derived from agricultural byproducts—A case study [DOI]
- 20 Adsorption of three azo reactive dyes by metal hydroxide sludge: effect of temperature, pH, and electrolytes [DOI]
- 21 Determination of the adsorption capacity of activated carbon made from coffee grounds by chemical activation with ZnCl and HPO [DOI]
- 22 Adsorption of dyes from aqueous solution — the effect of adsorbent pore size distribution and dye aggregation [DOI]
- 23 Activated carbons prepared from phosphoric acid activation of grain sorghum [DOI]
- 24 The adsorption of basic dye (Astrazon Blue FGRL) from aqueous solutions onto sepiolite, fly ash and apricot shell activated carbon: Kinetic and equilibrium studies [DOI]
- 25 Adsorption Equilibrium and Kinetics of Reactive Black 5 and Reactive Red 239 in Aqueous Solution onto Surfactant-Modified Zeolite [DOI]
- 26 Kinetic and equilibrium studies: Adsorption of food dyes Acid Yellow 6, Acid Yellow 23, and Acid Red 18 on activated carbon from flamboyant pods [DOI]
- 27 Removal of methylene blue from aqueous solution using cotton stalk, cotton waste and cotton dust [DOI]
- 28 Textural and chemical characterization of microporous carbons [DOI]
- 29 Error analysis of equilibrium studies for the almond shell activated carbon adsorption of Cr(VI) from aqueous solutions [DOI]
- 30 Treatability of a simulated disperse dye-bath by ferrous iron coagulation, ozonation, and ferrous iron-catalyzed ozonation [DOI]
- 31 Equilibrium, thermodynamic and kinetic studies on adsorption of commercial dye by activated carbon derived from olive-waste cakes [DOI]
- 32 Enhanced adsorption of metal ions onto functionalized granular activated carbons prepared from cherry stones [DOI]
- 33 Biosorptive Decolorization of Reactive Orange 16 Using the Waste Biomass of Corynebacterium glutamicum [DOI]
- 34 Effect of deashing rice straws on their derived activated carbons produced by phosphoric acid activation [DOI]
- 35 Kinetic and equilibrium adsorption of methylene blue and remazol dyes onto steam-activated carbons developed from date pits [DOI]
- 36 Adsorption Isotherms for Phenol Onto Activated Carbon [DOI]
- 37 COD removal from textile industry effluent: pilot plant studies [DOI]
- 38 ADSORPTION OF PHENOL FROM AQUEOUS MEDIA BY AN AGRO-WASTE (HEMIDESMUS INDICUS) BASED ACTIVATED CARBON [DOI]
- 39 Étude de l'élimination de bleu de méthylène dans l'eau par le charbon actif commercial CECA40 [DOI]
- 40 Chemical Production of Activated Carbon from Nutshells and Date Stones [DOI]
- 41 Prévision de l'adsorption de molécules organiques en solution aqueuse en fonctions de quelques caractéristiques physico-chimiques de charbons actifs [DOI]
Cited by 22
Ibsa Neme, Girma Gonfa, Chandran Masi · Heliyon · 2022
Nombamba Ouéda, Ibrahim Tchakala, Samadou Sanni · American Journal of Applied Chemistry · 2024
Marlena Gęca, Małgorzata Wiśniewska, Piotr Nowicki · Materials · 2024
Ali H. Jawad, Ramlah Abd Rashid, Khudzir Ismail · Desalination and Water Treatment · 2017
Samah Zaki Naji, Ching Thian Tye · Energy Conversion and Management: X · 2022
Kalu Ukanwa, Kumar Patchigolla, Ruben Sakrabani · Sustainability · 2019
Edwin A. Ofudje, Khairia Mohammed Al-Ahmary, Elham A. Alzahrani · BioResources · 2024
Alaa M Al-Ma’abreh, Dareen A Hmedat, Gada Edris · Adsorption Science & Technology · 2025
A. Vakili, A.A. Zinatizadeh, Z. Rahimi · Journal of Cleaner Production · 2023
Koffi A. Degbe, Diyakadola D. Bafai, Moursalou Koriko · Desalination and Water Treatment · 2021
Showing 20 of 22 known citations — external sources report more than can currently be individually listed.
Related research
- Effect of Modified Atmosphere Packaging and Multilayer Flexible Films on pH of Fresh Quail Meat — shares topic coverage
- Biochemical Changes and Sensory Evaluation of Soy Iru Produced Using Starter Culture — shares topic coverage
- Effects of PH and Storage Temperatures on Antibacterial Activity of Bacteriocin Produced by Lactic Acid Bacteria Isolated from OGI — shares topic coverage
- Hygienic Status of Cow Milk and Wara from Local Fulani Herdsmen in two Western States of Nigeria — shares topic coverage
- Assessment of Microbiological Quality of Yogurt Sold By Street Vendors in Onitsha Metropolis, Anambra State, Nigeria — shares topic coverage
Article metrics
Real usage data collected on this platform.
0
Page views
0
PDF downloads
0
Outbound clicks
22
Citations
Views by country
Approximate, from request IP at view time — not citizenship or institution. Countries with fewer than 5 views are grouped as "Other".
No views recorded yet.
Traffic sources
Referring site, by host.
No traffic recorded yet.
Views and downloads exclude known bots/crawlers. Citations combines this platform's own DOI-resolved index with each external source's own reported total — see Cited by above for individually listed citing works. Last refreshed 0 seconds ago.