Chemical Analyses of Volatile Compounds from Cuticular and Non-cuticular Abdominal Glands of African Weaver Ants (Oecophylla longinoda)
Chemical Science International Journal · pp. 304–312 · Published 1 Jan 2015
10.9734/ACSJ/2015/14255Abstract
Chemicals from the abdominal glands of African weaver ants (Oecophylla longinoda) were extracted with petroleum ether and fifteen pheromonal compounds were characterised using Gas Chromatography-Mass Spectrometry (GC/MS) Technique. The compounds analysed include decane (8.81%), undecane (5.97%), dodecane (4.52%), tridecane (1.75%), hexadecane (2.36%), methyl decanoate (3.31%), (3Z)-tetradec-3-ene (2.10 %), 2,6-dimethylheptadecane (13.29%), 11-octadecenoic acid methyl ester (17.01%), octanoic acid methyl ester (2.89%), 2-methyl nonadecane (11.92%), 1-fluorodecane (5.29%), (3E,11E)-tetradeca-3,11-dien-1-ol (12.02 %), cyclohexane-1,2-diol (3.71%) and 2-ethyl-1-decanol (5.07%). Fourier Transform-Infrared (FT-IR) analysis of the extract showed peaks at 1542.14, 1646.30, 2092.83, 2935.76 and 3427.62 cm-1 indicating the presence of alkene, alkyne, alkane and alcoholic compounds. These compounds consisted 50.72 % hydrocarbon, 23.21 % ester, 20.80 % alcohol and 5.29 % alkyl halide. The highest component was 11-octadecenoic acid methyl ester followed by 2,6-dimethylheptadecane. This investigation has shown that the cuticular abdominal chemicals derived from African weaver ants are mostly hydrocarbons, esters and alcohols which might be used by the insect as pheromone compounds.
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