Structural and Thermal Studies on Racemic PbC4H4O6•2H2O Single Crystal
Chemical Science International Journal · pp. 1–9 · Published 4 Dec 2018
10.9734/CSJI/2018/45004Abstract
Single crystals of racemic lead tartrate dihydrate, PbC4H4O6·2H2O, were grown at 308 K by the gel method using silica gel as the growth medium. Differential scanning calorimetry, thermogravimetric-differential thermal analysis, and X-ray diffraction measurements were performed on the single crystals. The space group symmetry (orthorhombic Pbca) and the structural parameters were determined at room temperature. The structure consisted of PbO8 polyhedra, C4H4O6 molecules, two independent H2O molecules, and zig-zag hydrogen-bonded chains along the a- and b-axes linked by O–H···O hydrogen bonds between adjacent molecules. Weight losses due to thermal decomposition of racemic PbC4H4O6·2H2O occurred in the temperature range of 300–1600 K. We suggested that the weight losses in the ranges of 300–900 K and 900–1600 K were caused by the evolution of gases from 2H2O and C4H4O5, and the evaporation of PbO, respectively.
Cited by 0
No indexed citations yet.
Related research
- Adamantane-Functionalized Phthalimide Scaffold: Pathways to Supramolecular Interactions and Drug Discovery — shares topic coverage
- Synthesis and Structure of 6-Acetyl-2-Arylhydrazone Derivatives of Thiazolo[3,2-a]Pyrimidine — shares topic coverage
- Luminescence of the Conjugate Bases of [2-(2-Hydroxyphenyl)phenyl]phosphinic Acid and Single-Crystal X-Ray Structure Determination of Sodium [2-(2-Hydroxyphenyl)phenyl]phosphinate — shares topic coverage
- Synthesis of Bipyridine Ether-Type Bifunctional Precursors — shares topic coverage
- Remarkable Influence of Structures around Rhenium (V) Centers Constructed in Polyoxotungstates for Methanol Dehydrogenation under Visible Light Irradiation — shares topic coverage
Article metrics
Real usage data collected on this platform.
0
Page views
0
PDF downloads
0
Outbound clicks
0
Citations
Views by country
Approximate, from request IP at view time — not citizenship or institution. Countries with fewer than 5 views are grouped as "Other".
No views recorded yet.
Traffic sources
Referring site, by host.
No traffic recorded yet.
Views and downloads exclude known bots/crawlers. Citations combines this platform's own DOI-resolved index with each external source's own reported total — see Cited by above for individually listed citing works. Last refreshed 0 seconds ago.